Nanoparticle-Based Cryogels from Colloidal Aqueous Dispersion: Synthesis, Properties and Applications

verfasst von
Hadir Borg, Irene Morales, Dirk Dorfs, Nadja C. Bigall
Abstract

Cryogels have morphological features that make them interesting for several applications such as catalysis, sensing or tissue engineering. Their interconnected network and open porous structure, build up by primary particles (such as inorganic nanocrystals or polymers), provide these materials with unique physical properties and high specific surface areas. While the library of cryogels is endless, widely used in the polymer chemistry field, in this review we will summarize the structure and properties, applications and challenges of inorganic nanocrystal-based cryogels obtained by freezing and freeze-drying an aqueous nanoparticle colloid. This fast, easy and versatile gelation method will be outlined, along with the corresponding macro-, micro- and nano-structures and gel morphologies that can be obtained, for example, by changing the freezing temperature or by using one nanoparticle system or nanoparticle mixtures. Their applications towards electrocatalysis, photocatalysis and photoelectrochemical sensing will be highlighted, as well as the challenges and prospects of these materials.

Organisationseinheit(en)
Institut für Physikalische Chemie und Elektrochemie
PhoenixD: Simulation, Fabrikation und Anwendung optischer Systeme
Laboratorium für Nano- und Quantenengineering
Externe Organisation(en)
Universität Hamburg
Typ
Übersichtsarbeit
Journal
CHEMNANOMAT
Band
10
Anzahl der Seiten
15
ISSN
2199-692X
Publikationsdatum
04.2024
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Biomaterialien, Erneuerbare Energien, Nachhaltigkeit und Umwelt, Energieanlagenbau und Kraftwerkstechnik, Werkstoffchemie
Ziele für nachhaltige Entwicklung
SDG 7 – Erschwingliche und saubere Energie
Elektronische Version(en)
https://doi.org/10.1002/cnma.202300532 (Zugang: Offen)