Origin and Manipulation of the Orientation of Colloidal 2D Nanoplatelets in Electrospun Fibers
Abstract
Stable jet electrospinning (SJES) enables the incorporation of fluorescent colloidal 2D nanoplatelets (NPLs) into polymer fibers, potentially for optical applications and manipulation of the orientation of the nanoplatelets. Three polymers with excellent optoelectronic properties are used as matrices, namely, poly(methyl methacrylate) (PMMA), cyclic olefin copolymer (COC), and copolycarbonate. The electrospinning parameters are optimized for the production of highly aligned microfibers by SJES. Polarization-resolved fluorescence microscopy is used to determine the orientation of the NPLs within the SJES fibers. For the PMMA fibers spun from a 35 wt % solution, a preferential vertical alignment of the NPL is found. We systematically investigate the origin of the NPL orientation using a series of polymer solutions with well-controlled rheology. During the SJES process, a die swell effect is observed when a highly concentrated viscoelastic polymer solution with a strong elastic component leaves the cannula. The resulting extensional flow causes the anisotropic NPLs to rotate and realign themselves through hydrodynamic forces. Conversely, for concentrations below the overlap concentration, the viscosity drops sharply, and shear thinning disappears, indicating a negligible elastic contribution. The COC and copolycarbonate systems─limited to suboverlap concentrations─exhibited only random NPL orientations. The vertical alignment of the NPLs in the fiber is therefore based on the viscoelastic properties of the non-Newtonian fluid and can be achieved only under strict and specific conditions.
Details
- Organisationseinheit(en)
-
PhoenixD: Simulation, Fabrikation und Anwendung optischer Systeme
Institut für Physikalische Chemie und Elektrochemie
- Externe Organisation(en)
-
Technische Universität Braunschweig
Eberhard Karls Universität Tübingen
Max-Planck-Institut für Multidisziplinäre Naturwissenschaften
- Typ
- Artikel
- Journal
- ACS Applied Optical Materials
- Band
- 4
- Seiten
- 129-139
- Anzahl der Seiten
- 11
- ISSN
- 2771-9855
- Publikationsdatum
- 23.01.2026
- Publikationsstatus
- Veröffentlicht
- Peer-reviewed
- Ja
- ASJC Scopus Sachgebiete
- Elektronische, optische und magnetische Materialien, Atom- und Molekularphysik sowie Optik, Spektroskopie
- Elektronische Version(en)
-
https://doi.org/10.1021/acsaom.5c00494 (Zugang:
Offen
)
